Cation Exchange Capacity
Also called: CEC
Cation exchange capacity (CEC) is the soil's ability to hold and exchange positively charged nutrients (cations) like calcium, magnesium, potassium, and ammonium. It is measured in milliequivalents per 100 grams (meq/100g) or centimoles per kilogram (cmol/kg). Sandy soils have low CEC (2–10); clay and high-organic-matter soils have high CEC (20–40+).
How Cation Exchange Capacity Works
CEC is essentially the soil's nutrient-holding capacity. Cations adhere electrostatically to negatively charged clay particles and humus surfaces; as plant roots absorb one cation (say K⁺), they release H⁺ that can displace another held cation back into the soil solution. Soils with high CEC can stockpile large amounts of nutrients without leaching them into groundwater, while low-CEC sandy soils lose fertilizer quickly after rain.
Typical ranges: sand 2–4 meq/100g, sandy loam 5–10, loam 10–15, clay loam 15–25, clay 25–40, organic/peat 50–100. A standard soil test reports CEC alongside base saturation — the percentage of the CEC occupied by Ca, Mg, K, and Na (versus acidity from H⁺ and Al³⁺). Optimal base saturation is roughly 65–80% Ca, 10–15% Mg, 3–7% K, <3% Na.
CEC determines fertilizer strategy. On high-CEC soils, a single large fertilizer application can last a full season. On low-CEC sandy soils, split applications (3–5 smaller doses through the growing season) prevent leaching losses. Building soil organic matter is the primary way to raise CEC over time — each 1% SOM increase adds roughly 2–4 meq/100g to total CEC.
Sources
- Cornell Cooperative Extension (2022). Cation exchange capacity and soil fertility.
- University of Minnesota Extension. CEC and base saturation.